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Caribbeans

(1,074 posts)
Tue Jan 28, 2025, 04:46 PM Tuesday

New water splitting catalyst makes green hydrogen without expensive metals


A 3D render simulating different layers, which is reminiscent of an electrolyzer. Credit: Milad Fakurian for Unsplash

New water splitting catalyst makes green hydrogen without expensive metals

ANEMEL | Techxplore.com | JANUARY 28, 2025

ANEMEL researchers have created a catalyst for water splitting that's efficient and stable, without relying on scarce platinum group metals (PGMs). The study, recently published in Energy & Environmental Science, reports a high-performance PGM-free catalyst for the cathode in water electrolysis, responsible for the reaction that creates green hydrogen.

Current anion exchange membrane (AEM) water electrolyzers rely on PGMs, which are scarce and expensive. Specifically, these metals are used as catalysts at the cathode, where hydrogen is generated. However, ANEMEL AEM electrolyzers avoid PGMs, opting instead for more abundant metals such as nickel. This is essential to enable the wide adoption of electrolyzers: it helps to decrease the cost of electrolyzer components and improve their recyclability, reducing waste and providing a competitive advantage.

This requires investigating innovative ways to ensure electrolyzers perform at least as well, if not better than, those made with PGMs. After all, platinum and other metals in this group offer excellent activity and stability, especially at high current densities in electrolyzer environments, something PGM-free catalysts still don't.


SEM images of the platinum-free catalysts that accelerate water splitting. Credit: Royal Society of Chemistry

To understand the achievement, the researchers define two concepts: self-supported catalyst and electrodeposition. A self-supported catalyst is a type of catalyst formed by growing it directly on a support, known as a gas diffusion layer (GDL). The GDL allows gases to diffuse while providing a conductive pathway and can be made of various materials. These include carbon paper, and nickel foam, felt and mesh..more
https://techxplore.com/news/2025-01-catalyst-green-hydrogen-expensive-metals.html
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New water splitting catalyst makes green hydrogen without expensive metals (Original Post) Caribbeans Tuesday OP
One is unlikely to pass an elementary chemistry class if one does not understand that... NNadir Tuesday #1
Worthless Nigrum Cattus Tuesday #2
please explain? Javaman Yesterday #3

NNadir

(35,008 posts)
1. One is unlikely to pass an elementary chemistry class if one does not understand that...
Tue Jan 28, 2025, 05:00 PM
Tuesday

Last edited Tue Jan 28, 2025, 09:02 PM - Edit history (1)

...a catalyst has no effect on thermodyamics. Splitting water requires the consumption of energy accompanied by energy losses to entropy.

A catalyst can change rates, but does not effect the Gibbs free energy of reaction.

Thus in all circumstances, the production of hydrogen destroys exergy. As it is, in almost all cases, energy derived from the combustion of fossil fuels, hydrogen is a filthy fuel.

Efforts to obscure this fact are presented not for the purpose of enlightenment but on the contrary are crude efforts to engage in dishonest marketing to further the interests of the fossil fuel industry, in all cases.

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